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When Nash arrived, he fired a lightning bolt at Vector in a rage. They began their Duel, with Vector having brought the [[Number ruins|ruins]] from his past life into the Barian World to serve as their arena. Vector used "[[Contract with Don Thousand]]" to give Nash a handicap, with Nash proceeding to fall into his trap and attack with "Silent Honor DARK" after Summoning it with "The Seventh One". Using a combination of "[[Chaos Rising]]" and "[[Chaos Caller]]", Vector brought out "[[Number C65: King Overfiend]]", "[[Number C104: Umbral Horror Masquerade]]", "[[Number C102: Archfiend Seraph]]" and "[[Number C103: Ragnafinity]]". Yuma arrived to support Nash at this point, but Nash persisted that they were enemies now. Vector used the power he had gained from the other Emperors to gain a new form. Nash survived Vector's assault with 100 Life Points and launched a counterattack using "[[Split Defender]]" and "[[Xyz Charge Up]]", ultimately resulting in him taking control of "King Overfiend" and using it to destroy "Umbral Horror Masquerade". This triggered Vector's true memories.<ref name="ep136">{{episode|Yu-Gi-Oh! ZEXAL|136|ref}}</ref> Once he remembered, Vector claimed to have realized the error of his ways, and activated "[[Xyz Discharge]]", allowing Nash to seize control of his comrades' "[[Number C10X|Chaos Over-Hundred Number]]s" at the cost of sending a card in his hand to the Graveyard. Attacking at Vector's wishes, he fell into his trap, "[[Trick Buster (anime)|Trick Buster]]", which destroyed all of Nash's monsters and dealt him 300 damage for each monster destroyed. However, Nash avoided the damage by activating the effect of his "[[Dream Shark]]". Vector, who was surprised to see him survive, accused Nash of not trusting him to start with, with Nash responding that he discarded the ability to trust when he shed his humanity. As the battle waged on, Vector performed a direct [[Chaos Xyz Evolution]], Summoning "[[Number C5: Chaos Chimera Dragon]]" with the effect of "[[Rank-Up-Magic Admiration of the Thousands]]", using "Chaos Numbers" in the Graveyard as Overlay Units. This card nearly defeated Nash, but he survived with "[[Depth Gardna]]" and then used "[[Infinity Tooth]]" to counter Vector's manipulation of his draws. He performed a second Barian's Chaos Draw and used the resulting "[[Depth Biter]]" to Summon "[[Number 73: Abyss Splash]]". Though Vector countered with "[[Overlay Burglary]]", Nash revealed a second "[[Rank-Up-Magic]]" in the form of "[[Rank-Up-Magic Quick Chaos]]", creating "[[Number C73: Abyss Supra Splash]]" and defeating Vector.<ref name="ep137">{{episode|Yu-Gi-Oh! ZEXAL|137|ref}}</ref>
As Vector went berserk with his power, Nash was surprised when [[Don Thousand]] appeared before them and tried to absorb Vector. He showed a little concern when Yuma ran to try and save Vector, urging Yuma to stop and that Vector had no soul; even if Yuma did save Vector, Vector would backstab him again. After Vector let himself be absorbed to protect Yuma and Don Thousand assumed his true form, Mizar arrived and Nash watched the Duel between him and Don Thousand. When Mizar lost, Nash mourned his death, which left him as the last of the Seven Barian Emperors. With his new form, Don Thousand stated that he will absorb Nash as well and challenged him and Yuma to a Duel. To avenge his comrades, Nash agreed to team up with Yuma against Don Thousand. Thousand quickly negated Yuma's Summon of "[[Number 39: Utopia|Utopia]]," revealing that the merging of the Barian and human Worlds was to enable him to control the [[Numeron Code]], allowing him to attack the Astral World directly.<ref name="ep138">{{episode|Yu-Gi-Oh! ZEXAL|138|ref}}</ref> Using his "[[Numeron]]" monsters, Thousand nearly defeated them, with Yuma and Nash surviving with "[[Half Unbreak]]" and "[[Cut-In Cutter Shark]]". Astral left to find the location of the "[[Numeron Network]]" card to help them. Nash baited Thousand into using "Numeron Network" to rewrite his "[[Aqua Jet]]", allowing him to use "Rank-Up-Magic - The Seventh One" to bring out both his "Over-Hundred Number" and its "Chaos" form. Thousand survived with "[[Numeron Wall]]", but by then Astral had found "Numeron Network" and put it onto the field, resulting in Nash destroying it with "[[Depth Eruption]]". Nash was tearful when it appeared that Astral would sacrifice himself to keep the resulting energy from destroying Earth, but [[Eliphas]] appeared and sacrificed himself in Astral's place.<ref name="ep139">{{episode|Yu-Gi-Oh! ZEXAL|139|ref}}</ref>
[[File:DoubleDestinyDraw.png|thumb|200px|right|[[Shining Draw]] and [[Barian's Chaos Draw]].]]
After learning of his true origins as Nash, he was able to wield his "[[Number 10X|Over-Hundred Number]]" - "[[Number 101: Silent Honor ARK]]"<ref name="ep123" /> and its upgraded "[[C (archetype)|C]]" form, the "[[Number C10X|Chaos Over-Hundred Number]]" "[[Number C101: Silent Honor DARK]]".<ref name="ep125" /> Upon defeating Quattro, he acquired "[[Number 15: Gimmick Puppet Giant Grinder]]", "[[Number 40: Gimmick Puppet of Strings]]" and "[[Number 88: Gimmick Puppet of Leo]]" and possibly their upgraded forms - "[[Number C15: Gimmick Puppet Giant Hunter]]", "[[Number C40: Gimmick Puppet of Dark Strings]]" and "[[Number C88: Gimmick Puppet Disaster Leo]]", respectively.<ref name="ep126" />
After defeating [[Don Thousand]] alongside Yuma, Nash absorbed all of Thousand's "Numbers". Among them were "[[Number 1: Numeron Gate of Numeron - Ekam]]", "[[Number 2: Numeron Gate of Numeron - Dve]]", "[[Number 3: Numeron Gate of Numeron - Trini]]", "[[Number 4: Numeron Gate of Numeron - Catvari]]", "[[Number 5: Des Chimera Dragon]]", "[[Number 6: Chronomaly Atlandis]]", "[[Number 9: Dyson Sphere]]", "[[Number 33: Chronomaly Machu Mech]]", "[[Number 43: Manipulator of Souls]]", "[[Number 46: Dragluon]]", "[[Number 58: Burner Visor]]", "[[Number 62: Galaxy-Eyes Prime Photon Dragon]]", "[[Number 64: Ronin Raccoon Sandayu]]", "[[Number 65: Djinn Buster]]", "[[Number 80: Rhapsody in Berserk]]", "[[Number 96: Dark Mist]]", "[[Number 102: Star Seraph Sentry]]", "[[Number 103: Ragnazero]]", "[[Number 104: Masquerade]]", "[[Number 105: Battlin' Boxer Star Cestus]]", "[[Number 106: Giant Hand]]" and "[[Number 107: Galaxy-Eyes Tachyon Dragon]]". Many of these also had "[[Number C]]" forms, including the "[[Number 10X|Over-Hundred Numbers]]". In addition, there was "[[Number C1000: Numerronius]]" and "[[Number iC1000: Numerronius Numerronia]]", which lacked a base "Number" form.<ref name="ep141">{{episode|Yu-Gi-Oh! ZEXAL|141|ref}}</ref>
After losing to Yuma, Nash gave [[Astral]] all the remaining "Number" cards before dying, resulting in Astral obtaining all 100 base "Numbers".<ref name="ep143">{{episode|Yu-Gi-Oh! ZEXAL|143|ref}}</ref>